Before generation
Use this diagnostic after learners know orbital capacities and filling order and need evidence about the first occupancy mismatch. It totals electrons, compares each orbital, and includes the familiar neutral chromium and copper exceptions. The report can guide a targeted discussion about capacity, sequence, or electron count without reducing the response to one score. It does not model ions, term symbols, spin diagrams, or spectra.
Worked example
The fictional iron response contains 1s2 2s2 2p6 3s2 3p6 4s2 3d6. Its occupancies total 26, matching atomic number 26, and every supported orbital agrees with the generated configuration. For chromium, the model would use 4s1 3d5, and for copper 4s1 3d10, rather than applying a simple 4s2 pattern without the common exceptions.
Formula or methodology
Electrons fill the implemented order 1s, 2s, 2p, 3s, 3p, 4s, 3d, and 4p with capacities 2, 2, 6, 2, 6, 2, 10, and 6. A neutral atom contains Z electrons. The generator then adjusts neutral chromium from 4s2 3d4 to 4s1 3d5 and copper from 4s2 3d9 to 4s1 3d10 before comparing orbital counts.
How to interpret the result
A match means the full entered occupancies agree with this neutral ground-state model and total Z electrons. A count mismatch can exist even if early orbitals look correct; an orbital mismatch points to the first visible difference in the comparison table. Some textbooks write 3d before 4s in the final notation, so evaluate occupancy rather than relying only on token order.
Common mistakes
Do not exceed s or p capacity, use atomic mass as electron count, omit inner orbitals when full notation is requested, apply neutral filling directly to transition-metal ions, or forget chromium and copper exceptions. Count all superscripts, distinguish filling sequence from final written convention, and use an orbital diagram when pairing and spin evidence are part of the task.